Occupational exposure to allyl chloride by National Institute for Occupational Safety and Health. Division of Criteria Documentation and Standards Development

Cover of: Occupational exposure to allyl chloride | National Institute for Occupational Safety and Health. Division of Criteria Documentation and Standards Development

Published by Dept. of Health, Education, and Welfare, Public Health Service, Center for Disease Control, National Institute for Occpational Safety and Health, for sale by the Supt. of Docs., U.S. Govt. Print. Off. in [Cincinnati], Washington .

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Subjects:

  • Allyl chloride -- Safety measures

Edition Notes

Book details

Other titlesCriteria for a recommended standard, occupational exposure to allyl chloride
SeriesCriteria for a recommended standard, DHEW publication ; no. (NIOSH) 76-204, DHEW publication -- no. (NIOSH) 76-204
The Physical Object
Paginationix, 87 p. :
Number of Pages87
ID Numbers
Open LibraryOL15397517M

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Get this from a library. Occupational exposure to allyl chloride. [National Institute for Occupational Safety and Health. Division of Criteria Documentation and Standards Development.].

Allyl chloride. Related Pages. Synonyms & Trade Names 1-Chloropropene, 3-Chloropropene, 3-Chloropropylene Exposure Routes inhalation, skin absorption, ingestion, skin and/or eye contact National Institute for Occupational Safety and Health. NIOSH Pocket Guide to Chemical Hazards.

Get this from a library. Occupational exposure to allyl chloride: criteria for a recommended standard. [National Institute for Occupational Safety and Health.]. Human data: It has been stated that a 1-hour exposure to ppm might cause serious effects [Deichmann and Gerarde ]. Revised IDLH: ppm Basis for revised IDLH: The revised IDLH for allyl chloride is ppm based on acute inhalation toxicity data in humans [Deichmann and Gerarde ] and animals [Boqin et al.

Select up to three search categories and corresponding keywords using the fields to the right. Refer to the Help section for more detailed instructions. RECOMMENDATIONS FOR AN ALLYL CHLORIDE STANDARD The National Institute for Occupational Safety and Health (NIOSH) recommends that employee exposure to allyl chloride in the workplace be controlled by adherence to the following sections.

The standard is designed to protect the health and safety of employees for up to a hourFile Size: 1MB. Employers must comply with a number of standards where employees are potentially exposed to chemical hazards.

These include OSHA's Permissible Exposure Limits PELs for about substances, which can be found as follows: General Industry: 29 CFRToxic and Hazardous Substances. Air contaminants and Z1, Z2, Z3 tables. Permissible Exposure Limits / OSHA Annotated Table Z-1; Note: This table only includes occupational exposure limits (OELs) for substances listed in the OSHA Z-1 Table.

OELs for hundreds of additional substances have been adopted by Cal/OSHA, NIOSH, and organizations periodically make revisions to their OELs and so they should be consulted directly for their most current values.

ALLYL CHLORIDE presents a serious fire and explosion hazard when exposed to heat, flame or oxidizing agents. Polymerizes violently and exothermically with Lewis acids (aluminum chloride, boron trifluoride, sulfuric acid) or metals (aluminum, magnesium, zinc, or galvanized metal) [MCA SD, ].

chloride (see General Remarks). Occupational exposure to allyl chloride may occur in its manufacture and in the production of epichlorohydrin, glycerol and a wide range of other chemical products.

Environmental occurrence Although the production and use of allyl chloride may result in its release to theFile Size: 84KB. ALLYL CHLORIDE PRODUCT STEARDSIP ANUAL Olin Allyl Chloride Table 1: Physical Properties of Olin Allyl Chloride1 Chemical Formula CH 2 = CHCH 2 CI CAS No.

EC No. EC Annex 1 No. X Molecular Weight Physical State/Appearance, STP Colorless Liquid Odor Unpleasant, Pungent Odor Boiling Point @ torr ( kPa)a. We searched MEDLINE and EMBASE for epidemiologic studies on occupational exposure to methylene chloride and risk of cancer. Estimates of study-specific odds ratios (ORs) were calculated using inverse-variance-weighted fixed-effects models and random-effects models.

Statistical tests for heterogeneity were applied. We summarized data from five cohort studies and 13 Cited by: Occupational exposure exists for people working in the production of allyl chloride, epichlorohydrin, and synthetic glycerin.

(1) Individuals may be exposed to allyl chloride through breathing contaminated air or through skin contact. (1) Assessing Personal Exposure. Nevertheless, it is anticipated that allyl chloride will trigger health problems of workers as occupational diseases.

To predict risks for workers' health, especially occupational cancers, and to improve the assessment of hazardous effects, we recommend additional studies that focus on lung exposure and the long-term effects of these low-level Cited by: 3. Allyl alcohol (IUPAC name: propenol) is an organic compound with the structural formula CH 2 =CHCH 2 OH.

Like many alcohols, it is a water-soluble, colourless is more toxic than typical small alcohols. Allyl alcohol is used as a raw material for the production of glycerol, but is also used as a precursor to many specialized compounds such as flame-resistant materials, drying Appearance: colorless liquid.

- Allyl chloride and epichlorohydrin are toxic by ingestion, inhalation or contact with skin and eyes. Exposures can occur at allyl chloride and epichlorohydrin manufacturing facilities or at manufacturing facilities that handle them.

Exposure may also occur in the event of a transportation incident. Manufacturing processes or systems where allylFile Size: 48KB. The effects of occupational exposure to allyl chloride were studied in 45 male and 15 female workers in an allyl chloride manufacturing plant who were exposed to concentrations of allyl chloride ranging from ppm for 16 months (Hausler and Lenich, as reported in NIOSH, ).

Allyl Chloride CAS Number Appearance Clear liquid Assay % min. Specific Gravity (Water = 1) Odour Pungent. Irritant. Sharp Water more soluble in water; log(oil/water) = Solubiliy. ALLYL CHLORIDE INTERIM: 05/ 3 1 PREFACE 2 3 Under the authority of the Federal Advisory Committee Act (FACA) P.

of 4the National Advisory Committee for Acute Exposure Guideline Levels for Hazardous. Symbol which looks like a small house Solid circle with an upward pointer in it. Jump to content. Title(s): Occupational exposure to allyl chloride: criteria for a recommended standard.

Country of Publication: United States Publisher: [Cincinnati]: U. Dept. of Health, Education, and Welfare, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health ; Washington: for sale by the Supt. Allyl alcohol (IUPAC name: propenol) is an organic compound with the structural formula CH 2 =CHCH 2 OH.

Like many alcohols, it is a water-soluble, colourless liquid. It is more toxic than typical small alcohols. Allyl alcohol is used as a raw material for the production of glycerol, but is also used as a precursor to many specialized compounds such as flame-resistant materials, drying.

Exposure CALL FOR MEDICAL AID. VAPOR POISONOUS IF INHALED OR IF SKIN IS EXPOSED. Irritating to eyes, nose and throat. ALLYL CHLORIDE ALC SATURATED LIQUID DENSITY Temperature (degrees F) Pounds per cubic foot 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 File Size: 18KB.

Occupational exposure to allyl chloride: NIOSH: NIOSH: Occupational exposure to alkanes: John Finklea: NIOSH: Occupational exposure to airborne substances harmful to health: ILO: ILO: Occupational exposure to airborne substances harmful to health: Dr A.

Rothan: ILO: Occupational exposure to. Occupational safety and health guidelines for chemical hazards. suppl. 3, U.S. Department of 2-butoxyethanol ACGIH acrolein acrylic acid alcohol allyl chloride American Conference anisidine Autoignition temperature azinphos-methyl baseline health status benomyl biological monitoring bismuth telluride boron boron tribromide bromine.

The toxicity of allyl chloride was determined in several species of animals. The oral LD 50 was mg/kg in the mouse and mg/kg in the rat. The 2-hr LC 50 's in the mouse, rat, guinea pig, rabbit, and cat were, and mg/kg, respectively. The target organs were the liver, kidneys, and nervous system, and the lungs in the inhalation by: The thermochemistry of the isomerization of 3-halopropenes (allyl halides) to 1-halopropenes; entropy and enthalpy of formation contribution of the C d-(H)(X) group, J.

Chem. Thermodyn.,5, OEHHA Air Toxics Hot Spots Program Technical Support Document for Cancer Potencies. Appendix B. Chemical-specific summaries of the information used to derive unit risk and cancer potency values. Updated OEHHA Final Statement of Reasons. Occupational exposure to allyl bromide may occur through inhalation and dermal contact with this compound at workplaces where allyl bromide is produced or used.

Monitoring data indicate that the general population may be exposed to allyl bromide via inhalation of ambient air, and dermal contact with this compound and other products containing.

Increasing the Production of 3-ChloroPropene (Allyl Chloride) in Unit Background You are currently employed by the TBWS Corp. at their Beaumont, Texas plant, and you have been assigned to the allyl chloride facility.

A serious situation has developed at the plant, and youFile Size: KB. ENEA - ALLYL CHLORIDE ALLYL CHLORIDE Safety Data Sheet ENEA Date of issue: 06/25/ Version: 06/25/ EN (English US) SDS ID: ENEA Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertakingFile Size: KB.

Acrylamide is a colorless, odorless, crystalline amide that polymerizes rapidly and can form as a byproduct during the heating of starch-rich foods to high mide is used in the production of polymers mainly in the water treatment industry, pulp and paper industry and textile treatment industry and is used as a laboratory reagent.

The polymer is nontoxic, but exposure to the. Occupational exposure to allyl chloride may occur through inhalation and dermal c ontact with this 20 compound at workplace s where allyl chlor ide is produced or used [6 ]. Guide to Occupational Exposure Values. This companion document to the ACGIH ® TLVs ® and BEIs ® book serves as a readily accessible reference for.

CAS Number Synonym(s) 3-Chloropropene; 3-Chloropropene; Chloropropylene. Occurence(s)/Use(s) Production of epichlorohydrin, glycerin, pesticides, and pharmaceuticals. Occupational Exposure To Chemicals: HazMap was retired.

The content of Haz-Map is still provided by the original content provider: Risk Assessment: TOXNET's IRIS. Allyl bromide (3-bromopropene) is an organic is an alkylating agent used in synthesis of polymers, pharmaceuticals, and other organic compounds.

Physically, allyl bromide is a colorless liquid with an intense, acrid, and persistent smell. Allyl bromide is more reactive but more expensive than allyl chloride, and these considerations guide its al formula: C₃H₅Br. (a) The unshaded area on this page lists PELs from OSHA Table Z-1 in 29 CFR The shaded area of this page lists other occupational exposure limits (OELs) from Cal/OSHA, NIOSH, and ACGIH®.

Allyl Alcohol C3H6O – 35 mustard TWA = Skin TWA = 2 – 12 Allyl Chloride C3H5CI – pungent TWA = 1 STEL = 2 Skin TWA = 1 – 13 Allyl Isothiocyanate C4H5NS – irritating – – STEL = 1 Skin DSENFile Size: KB. Dimethylamine ([greater than or equal to]%), allyldimethylamine (>%), allyl chloride (>%), allyl alcohol (>%), and allyl aldehyde (>%) were purchased from Sigma-Aldrich (USA).

Quantitative Analysis of Volatile Impurities in Diallyldimethylammonium Chloride Monomer Solution by Gas Chromatography Coupled with Liquid-Liquid. 4 Epichlorohydrin 1 Acute Exposure Guideline Levels. PREFACE. Under the authority of the Federal Advisory Committee Act (FACA) P.L.

ofthe National Advisory Committee for Acute Exposure Guideline Levels for Hazardous Substances (NAC/AEGL Committee) has been established to identify, review, and interpret relevant toxicologic and other scientific data and develop AEGLs for high.Sodium chloride is indicated for multiple conditions including corneal edema, elective termination of pregnancy, heat stroke, low blood sodium, shock due to low volume, and nasal irritation.

Sodium is the principle cation of extracellular fluid and chloride is the principle anion of extracellular fluid.Here you can find all of the regulations and regulatory lists in which this substance appears, according to the data available to ECHA.

This substance has been found in the following regulatory activities (directly, or inheriting the regulatory context of a parent substance).

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